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Pubmed ID :28874048
Publication Date : 2017/09/06

Oxidative Heck Reaction as a Tool for Para-selective Olefination of Aniline: A DFT Supported Mechanism.


This study describes the first para-selective palladium-catalyzed alkenylation of tertiary amines. This regioselective C-H activation was conducted without any chelation moieties. A series of olefins were reacted under mild reaction conditions at 60 °C, and the corresponding products were obtained in good yields with high selectivity.

Authors : Moghaddam Firouz Matloubi , Pourkaveh Raheleh , Karimi Ashkan ,

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